First published online as a Review in Advance on January 31, 2006WATER, MELTING, AND THE DEEP EARTH H2O CYCLE
Marc M. HirschmannDepartment of Geology and Geophysics, University of Minnesota, Minneapolis, Minnesota 55455-0219; email:
Marc.M.Hirschmann-1@umn.edu Abstract Hydrous melting driven by changes in H2O storage capacity may occur in a variety of settings in the mantle, including in oceanic basalt sources and in deeper regions above and below the transition zone. The 50–200 ppm H2O in the upper mantle likely derives from a blend of sources that may include residues of hydrous partial melting, either in the deep mantle and/or beneath arcs or oceanic islands. Relative to the large storage capacity in the transition zone, low storage capacities above and below may lead to hydrous melting for material upwelling through 410 km or downwelling through 670 km. The apparently very low storage capacity of the lower mantle (<20 ppm H2O) may force melting even if downwelling rocks have normal upper mantle H2O (50–200 ppm) concentrations. Very low storage capacity in the lower mantle, if verified experimentally, presents a challenge to the view that the H2O-rich sources of oceanic island basalts reside in the lower mantle.
Acronyms
BSE: bulk silicate Earth
DHMS: dense hydrous magnesium silicate
FTIR: Fourier transform infrared spectroscopy
MORB: mid-ocean ridge basalts
NAM: nominally anhydrous mineral
OIB: oceanic island basalt
SIMS: secondary ion mass spectrometry
Most recent citing papers (via CrossRef)
Mantle reflectivity structure beneath oceanic hotspots
Geophysical Journal International (2009)
Mantle transition zone structure along a profile in the SW Pacific: thermal and compositional variations
Geophysical Journal International 176(1):113-125 (2009)
Hydrous silicate melt at high pressure
Nature 452(7190):983-986 (2008)

Geodynamic Significance of Seismic Anisotropy of the Upper Mantle: New Insights from Laboratory Studies
Annual Review of Earth and Planetary Sciences 36:59-95 (2008)

The Redox State of Earth's Mantle
Annual Review of Earth and Planetary Sciences 36:389-420 (2008)